Activating Unreactive Substrates: The Role of Secondary Interactions

Activating Unreactive Substrates: The Role of Secondary Interactions

By: F.Ekkehardt Hahn (editor), Carsten Bolm (editor)Hardback

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The use of secondary interactions for the activation of non-reactive substrates constitutes a new and modern approach in catalysis. This first comprehensive treatment of this important research field covers the entire field and reveals the links between the various chemical disciplines. It thus adopts an interdisciplinary approach, making it of interest to the whole chemical community. A must for organic, inorganic, catalytic and complex chemists, as well as those working with/on organometallics.

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About Author

Carsten Bolm became Professor of Organic Chemistry at the University of Marburg (Germany) in 1993, and since 1996 he has been full professor for Organic Chemistry at the RWTH Aachen University (Germany). He held visiting professorships at universities in Madison, Wisconsin (USA), Paris (France), Florence (Italy), Milan (Italy), Namur (Belgium) and Tokyo (Japan). His list of awards include the Heinz-Maier-Leibnitz prize, the ADUC-Jahrespreis for habilitands, the annual prize for Chemistry of the Akademie der Wissenschaften zu Gottingen, the Otto-Klung prize, the Otto-Bayer award, a fellowship of the Japan Society for the Promotion of Science, and the Prix Franco-Allemand. With Wiley-VCH he edited books (together with Matthias Beller) on Transition Metals for Organic Chemistry and (together with Takeshi Toru) on Organosulfur Chemistry in Asymmetric Synthesis. Ekkehardt Hahn became Professor of Inorganic Chemistry at the Free University of Berlin in 1992. Since 1998 he is full professor of Inorganic Chemistry at the University of Munster (Germany). He held visiting professorships at the University of California, Berkeley (USA), the Universidad de Zaragoza (Spain), the National University of Singapore, and the Institute of Organic Chemistry of the Academia Sinica, Shanghai (PR China). His lists of awards includce a Karl Winnacker Fellowship and the election to the Academia de Ciencas Exactas, Fisicas, Quimicas y Naturales de Zaragoza, Spain. He holds a Julius von Haast visiting Professorship at the University of Auckland (New Zealand) and since 2004 serves as Permanent Secretary of the International Conference on Organometallic Chemistry


CHEMISTRY OF METALATED CONTAINER MOLECULES Introduction Metalated Container Molecules: A Brief Overview Metalated Container Molecules of Binucleating Supporting Ligands THE CHEMISTRY OF SUPERBASIC GUANIDINES Properties of the Guanidine Functionality Design of Superbasic Proton Sponges Some Perspectives in Proton Sponge Chemistry Multidentate Superbasic Guanidine Ligands as Receptors for Metal Cations The Chemistry of Guanidine Copper Complexes The Chemistry of Guanidine Zinc Complexes IRON COMPLEXES AND DIOXYGEN ACTIVATION Introduction Dinuclear Iron Peroxo Complexes Tripodal Tetradentate Ligands and Derivatives Monomuclear Iron Peroxo Complexes Mononuclear Iron Oxo Species Work in Progress TUNING OF STRUCTURES AND PROPERTIES OF BISPIDINE COMPLEXES Introduction Jahn-Teller Isomerism with Copper(II) Bispidines Stabilization of High-Spin Ferryl Complexes Jahn-Teller-Distorted Cobalt(III) Complexes NOVEL PHOSPHORUS AND NITROGEN DONOR LIGANDS BEARING SECONDARY FUNCTIONALITIES FOR APPLICATIONS IN HOMOGENEOUS CATALYSIS Introduction Phosphine Ligands Nitrogen Donor Ligands Without Phosphorus Sites SQUARE-PYRAMIDAL COORDINATED PHOSPHINE IRON FRAGMENTS: A TALE OF THE UNEXPECTED Introduction Polyphosphine Ligands with Three and Four Coordinating Arms C-P Bond Activation and Agostic Interactions in Iron Complexes of Polypodal Phosphine Ligands Mechanistic Considerations REGIOSELECTIVE CATALYTIC ACTIVITY OF COMPLEXES WITH NH,NR-SUBSTIUTED HETEROCYCLIC CARBENE LIGANDS Introduction Concept of Regioselective Substrate Activation Synthesis of Complexes with NH,NR-Stabilized NHC Ligands Preparation of Substrates for Catalytic Experiments Catalysis Experiments FUNCTIONALIZED CYCLOHEPTATRIENYL-CYCLOPENTADIENYL SANDWICH COMPLEXES AS BUILDING BLOCKS IN METALLO-SUPRAMOLECULAR CHEMISTRY Introduction Syntheses and Electronic Structure of Group 4 Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes Syntheses and Reactivity of Ansa-Cycloheptatrienyl-Cyclopentadienyl Complexes Ring-Opening Reactions of Ansa-Cycloheptatrienyl-Cyclopentadienyl Complexes Phosphine-Functionalized Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes MONOSACCHARIDE LIGANDS IN ORGANOTITANIUM AND ORGANOZIRCONIUM CHEMISTRY Introduction Synthesis of Organotitanium Carbohydrate Compounds Organotitanium Carbohydrate Compounds for Use in Catalytic Reactions: Polymerization of Ethylene Intramolecular Hydroamination of Aminoalkenes Organozirconium Carbohydrate Compounds Amine Exchange Chiral Recognition REACTIONS OF C-F BONDS WITH TITANOCENE AND ZIRCONOCENE: FROM SECONDARY INTERACTION VIA BOND CLEAVAGE TO CATALYSIS Introduction and Background Secondary Interactions with C-F Bonds Formation of M-F Bonds Stoichiometric Formation of Zr-H Bonds Catalytic Formation of Zr-H Bonds BISAZINES IN THE COORDINATION SPHERE OF EARLY TRANSITION METALS Introduction Results and Discussion BIFUNCTIONAL MOLECULAR SYSTEMS WITH PENDANT BIS(PENTAFLUOROPHENYL)BORYL GROUPS: FROM INTRAMOLECULAR CH-ACTIVATION TO HETEROLYTIC DIHYDROGEN SPLITTING Introduction Bifunctional Zirconum/Boron Systems Bifunctional Group 9 Metal/Boron Systems Bifunctional Phosphorus/Boron Systems RUTHENIUM-CONTAINING POLYOXOTUNGSTATES: STRUCTURE AND REDOX ACTIVITY Introduction The Organoruthenium(II)-Containing 49-Tungsto-8-Phosphate[{K(H2O)}3{Ro(p-cymene)()H2O)}4P8W49O186(H2O)2]27- The Mono-Ruthenium(III)-Substituted Keggin-Type 11-Tungstosilicate [alpha-SiW11O39Ru111(H2=)]5- and its Dimerization FROM NO TO PEROXIDE ACTIVATION BY MODEL IRON(III) COMPLEXES Introduction NO Activation by Fe(III) Complexes Peroxide Activation by Fe(III) Complexes SYNTHETIC NITROGEN FIXATION WITH MOLYBDENUM AND TUNGSTEN PHOSPHINE COMPLEXES: NEW DEVELOPMENTS Introduction Mechanistic Investigation of the Chatt Cycle New Phosphine and Mixed P/N Ligands for Synthetic Nitrogen Fixation DIRECTED C-H FUNCTIONALIZATIONS Introduction Results and Discussion DEVELOPMENT OF NOVEL RUTHENIUM AND IRON CATALYSTS FOR EPOXIDATION WITH HYDROGEN PEROXIDE Introduction Development of Epoxidation Catalysts Using H2O2 PENTACOORDINATING BIS(OXAZOLINE) LIGANDS WITH SECONDARY BINDING SITES FLAVIN PHOTOCATALYSTS WITH SUBSTRATE BINDING SITES Introduction Templated Flavin Photoreductions Templated Flavin Photooxidations NEW CATALYTIC CU-, PD- AND STOICHIOMETRIC MG-, ZN-MEDIATED BOND ACTIVATIONS Introduction Catalytic Activation Stoichiometric Activation FROM COBALT(II)-ACTIVATED MOLECULAR OXYGEN TO HYDROCYMETHYL-SUBSTITUTED TETRAHYDROFURANS Introduction Thermochemical Considerations Cobalt(II)-Diketonate Complexes Reactivity Stereoselectivity Survey A Derivative of Magnosalicin Expanding the Scope REGIODIVERGENT EPOXIDE OPENING Epoxide Opening via Nucleophilic Substitution: Limitations Arising from the SN2-Mechanism Regiodivergent Epoxide Opening (REO): Mechanistic Implications, Synthetic Potential, and Aspects of Catalyst Design Reductive Epoxide Opening via Electron Transfer from Titanocene(III) Reagents Synthetic Realization of Titanocene-Catalyzed REO SUPRAMOLECULAR CONTAINERS: HOST-GUEST CHEMISTRY AND REACTIVITY Introduction M4L4Tetrahedra Amino Acid-Bridged Dinuclear Titanium(IV) Complexes as Metalloenzyme Mimicry SELF-ASSEMBLY OF DINUCLEAR HELICAL METALLOSUPRAMOLECULAR COORDINATION COMPOUNDS Introduction The Concept of Diastereoselective Self-Assembly of Dinuclear Helicates Synthesis of Building Blocks for the Covalent Assembly of Bis(Chelating) Ligands Synthesis of Bis(Chelating) Ligands and Their Dinuclear Metal Complexes

Product Details

  • publication date: 28/01/2009
  • ISBN13: 9783527318230
  • Format: Hardback
  • Number Of Pages: 481
  • ID: 9783527318230
  • weight: 1046
  • ISBN10: 3527318232

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