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This text explores nonbranching reactions, including in-depth information on the inhibitors of free radical polymerisation and the mechanisms of antioxidants on oxidationprocesses. Auto-initiated chain reactions are also explored, with detailed descriptions on the kinetics, mechanisms, and inhibition of the autoxidation of organic compounds, A special chapter deals with the synergism of antioxidant actions. The theory of chain-branching reactions is investigated, and a large amount of new experimental data concerning the use of chemical additives to regulate combustion processes is also presented, including the mode of chain thermal explosion.
Part I. Straight Chain Reactions: Fundamentals of the Theory of Chain Reactions 1. Inhibition of Striaght Chain Reactions in the Gas Phase 2. Inhibitors of Polymerization 3. Kinetics of the Inhibited Chain Oxidation by Phenols and Aromatic Amines 4. Cyclic Mechanisms of Chain Termination Upon Oxidation of Organic Compounds Part II: Degenerate Chain Branching Reactions: Kinetics and Mechanisms of Autoxidation of Organic Compounds 5. Kinetics of Autoxidation of Organic Compounds Inhibited by Peroxyl Radical Acceptors 6. Hydroperoxide-Decomposing Inhibitors of Oxidation 7. Synergism of Antioxidants Part III: Branching Chain Processes: Fundamentals of the Theory of Branching Chain Processes 8. Inhibition of Ignition and Combustion
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- ID: 9789069940021
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