The main theme of this title is that of the mechanisms by which substitution, electron transfer, and other sundry other reactions of inorganic species take place. There is full coverage of organometallic systems, including consideration of mechanistic details of homogeneous catalysis, due attention to bioinorganic systems, and a sprinkling of examples from such areas as pharmacology and geochemistry.
* Reactions in Solution. * Substitution Reactions: General Considerations. * Substitution at Two-, Three-, Four-, and Five-Coordinate Reaction Centres. * Substitution in Octahedral Complexes. * Stereochemical Change; Introduction; Classification of Steroechemical Change. * Substitution Reactions of Carbonyls and Related Compounds. * Solvent Exchange and Complex Formation. * Medium Effects. * Oxidation-Reduction Reactions. * Activation, Addition, Insertion, and Catalysis.
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- ID: 9780582236776
1st Revised edition
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