Inorganic Reactions and Methods: v. 13 Formation of Bonds to Group-I, -II, and -IIIB Elements (Inorganic Reactions and Methods)

Inorganic Reactions and Methods: v. 13 Formation of Bonds to Group-I, -II, and -IIIB Elements (Inorganic Reactions and Methods)

By: J. J. Zuckerman (author)Hardback

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Inorganic Reactions and Methods Volume 13 Founding Editor J. J. Zuckerman Editor A. P. Hagen

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Contents

How to use this book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 13; 6. Formation of the Bonds to Group--IIIB (B, AI, Ga, In, TI) Elements; 6.1. Introduction; 6.2. Formation of the Group--IIIB--Group--IIIB Element (B, AI, Ga, In, TI) Bond; 6.2.1. Introduction; 6.2.2. from Group--IIIB Halides; 6.2.2.1. by Comproportionation with the Group--IIIB Element or Its Univalent State; 6.2.2.2. by Reduction with Metals; 6.2.2.3. by Disproportionation of Dinuclear Compounds; 6.2.2.4. by Metal Atom and Related Reactions; 6.2.3. in Combination with Group--VIB Elements; 6.2.4. from Group--IIIB--Group--IVB Bonds; 6.2.5. from Gallium in Halogen Acid Media; 6.3. Formation of Group--IIIB--Group IA or Group--IIA Bonds; 6.4. Formation of Group III--B--Group--IB or Group--IIB Bonds; 6.5. Formation of Group--IIIB--Transition-- or --Inner Transition--Metal Bonds; 6.5.1. Introduction; 6.5.2. Formation from Group--IIIB Halides; 6.5.2.1. by Reaction with Neutral Metal Bases; 6.5.2.2. by Reaction with Anionic Metal Bases; 6.5.2.3. by Oxidative--Addition Reactions; 6.5.3. Formation from Other Group--IIIB Compounds; 6.5.3.1. by Reaction with Neutral Metal Bases; 6.5.3.2. by Reaction with Anionic Metal Bases; 6.5.3.3. by Oxidative Addition Reactions.; 6.5.3.4. by Reaction with Metal Halides; 6.6. The Formation of the Group III--Group 0 Element Bond; 6.7. Formation of Borides; 6.7.1. Introduction; 6.7.2. Existence and Crystal Chemistry of Borides; 6.7.2.1. Borides with Isolated Boron Atoms; 6.7.2.1.1. Metal Frame Structures - Topological Packed Structures.; 6.7.2.1.2. Substitutional Metal Borides.; 6.7.2.1.3. Metal Boride Structures (Isolated Boron Atoms).; 6.7.2.2. Borides with Boron Chains; 6.7.2.2.1. Structure Types with Chain Fragments (B 2 , B 3 , B 4 Groups).; 6.7.2.2.2. Ternary Borides with Boron--Boron Chain Formation.; 6.7.2.3. Borides with Two--Dimensional Boron Networks; 6.7.2.4. Borides with Three--Dimensional Boron Networks; 6.7.2.4.1. ThB 4 --Type Tetraborides.; 6.7.2.4.2. CaB 6 --Type Hexaborides.; 6.7.2.4.3. UB 12 --Type Dodecaborides.; 6.7.2.4.4. YB 66 --Type Borides.; 6.7.2.4.5. Other Types.; 6.7.2.4.6. Summary.; 6.7.2.5. Solid Solution of Transition and Inner Transition Metals in Boron; 6.7.2.5.1. The Solubility in the Various Modifications of Boron.; 6.7.2.5.2.Solid Solutions in beta--Rhombohedral Boron.; 6.7.2.5.3. Crystallographic Data on Solid Solutions of beta--Rhombohedral Boron.; 6.7.3. Preparation of Borides; 6.7.3.1. by Direct Combination of the Elements; 6.7.3.2. by Reduction of a Metal Compound and Boron Halide with Hydrogen; 6.7.3.3. by Fused--Salt Electrolysis; 6.7.3.4. by Reduction of a Metal Oxide or Other Metal Compound Using Carbon, Boron or Boron Carbide; 6.7.3.5. by Reduction of Boron Oxide or Boron Halides with Metals; 6.7.3.6. by Low--Temperature Precipitation of Borides from Solution; 6.7.3.7. by Other Methods; 6.7.4. Crystal Growth of Borides; 6.7.4.1. by Gas--Phase Methods; 6.7.4.1.1. by Chemical Vapor Deposition (CVD).; 6.7.4.1.2. Crystal Growth of Borides by Chemical Vapor Transport.; 6.7.4.2. Liquid--Phase Method; 6.7.4.2.1. Crystal Pulling.; 6.7.4.2.2. Floating--Zone Technique.; 6.7.4.2.3. Flame--Fusion Technique.; 6.7.4.3. Flux Methods; 6.7.5. Sintering Methods; 6.7.5.1. Sintering of Pure Borides; 6.7.5.1.1. Comminution of Powders.; 6.7.5.1.2. Compacting or Molding of Powders.; 6.7.5.1.3. Sintering: Miscellaneous.; 6.7.5.1.4. Sintering: Characteristics.; 6.7.5.1.5. Sintering of Boride--Metal Composites.; 6.7.5.2. Hot Pressing of Pure Borides; 6.7.5.2.1. Technology of Hot Pressing.; 6.7.5.2.2. Hot--Pressing Characteristics of Pure Borides.; 7. Formation of Bonds to the Group--IA (Li, Na, K, Rb, Cs, Fr) or Group--IIA (Be, Mg, Ca, Sr, Ba,Ra) Metals; 7.1. Introduction; 7.2. Formation of Group--IA (Li, Na, K, Rb, Cs, Fr) or Group--IIA (Be, Mg, Ca, Sr, Ba, Ra)--Group--IA (Li, Na, K, Rb, Cs, Fr) or --Group--IIA (Be, Mg, Ca, Sr, Ba, Ra) Metal Bonds; 7.2.1. Introduction; 7.2.2. in the Group--IA Elements; 7.2.2.1. in Lithium; 7.2.2.1.1. Industrial Manufacture.; 7.2.2.1.2. The Purity of Commercial Lithium.; 7.2.2.1.3. The Purification of Lithium.; 7.2.2.1.4. Analysis of Lithium for Impurities.; 7.2.2.2. in Sodium; 7.2.2.2.1. Industrial Manufacture.; 7.2.2.2.2. The Purity of Commercial Sodium.; 7.2.2.2.3. The Purification of Sodium.; 7.2.2.2.4. Analysis of Sodium for Impurities.; 7.2.2.3. in Potassium; 7.2.2.3.1. Industrial Manufacture.; 7.2.2.3.2. Impurities in Commercial Potassium.; 7.2.2.3.3. Purification of Potassium.; 7.2.2.3.4. Analysis of Potassium.; 7.2.2.4. in Rubidium and Cesium; 7.2.2.4.1. Industrial Manufacture.; 7.2.2.4.2. Purity of the Commercial Metals.; 7.2.2.4.3. Purification.; 7.2.2.4.4. Analysis for Impurities.; 7.2.2.5. In Francium; 7.2.3. in the Group--IIA Elements; 7.2.3.1. in Beryllium; 7.2.3.1.1. Industrial Manufacture.; 7.2.3.1.2. Laboratory Preparation.; 7.2.3.1.3. Purity and Purification.; 7.2.3.2. in Magnesium; 7.2.3.2.1. Industrial Manufacture.; 7.2.3.2.2. Laboratory Preparation.; 7.2.3.2.3. Purity and Purification.; 7.2.3.3. in Calcium; 7.2.3.3.1.Industrial Manufacture.; 7.2.3.3.2. Laboratory Preparation.; 7.2.3.3.3. Purity and Purification.; 7.2.3.4. in Strontium and in Barium; 7.2.3.4.1. Industrial Manufacture.; 7.2.3.4.2. Laboratory Preparation.; 7.2.3.4.3. Purity and Purification.; 7.2.4. Formation of Alloys Between Group--IA Elements; 7.2.4.1. Binary Alloys; 7.2.4.1.1. Phase Diagrams.; 7.2.4.1.2. Compound Formation.; 7.2.4.1.3. Preparations.; 7.2.4.2. Multicomponent Alloys; 7.2.5. Formation of Alloys Between Group--IIA Elements; 7.2.5.1. Binary Alloys; 7.2.5.1.1. Phase Diagrams.; 7.2.5.1.2. Compound Formation.; 7.2.5.1.3. Preparations.; 7.2.6. Formation of Alloys Between Group--IA and Group--IA Elements; 7.2.6.1. Binary Alloys; 7.2.6.1.1. Phase Diagrams.; 7.2.6.1.2. Compound Formation.; 7.2.6.1.3. Preparations.; 7.3. Formation of the Group--IA or --IIA-- Group--IB or --IIB Element Bonds; 7.3.1. Formation of the Group--IA--Group--IB Element Bonds; 7.3.1.1. Phase Diagrams; 7.3.1.1.1. Lithium Systems.; 7.3.1.1.2. Sodium Systems.; 7.3.1.1.3. Potassium Systems.; 7.3.1.1.4. Rubidium and Cesium Systems.; 7.3.1.2. Compound Formation; 7.3.1.3. Preparations; 7.3.1.3.1. of Alkali--Metal--Copper Compounds.; 7.3.1.3.2. of Alkali--Metal--Silver Compounds.; 7.4.1.1. in Metallic Systems; 7.4.1.2. in Coordination Compounds Containing a Group--IA -- Transition--Metal or Inner--Transition--Metal Bond; 7.4.1.2.1. in Synthesis of Compounds Containing Lithium Bonded to a Transition Metal.; 7.4.1.2.2. in Synthesis of Compounds Containing Sodium Bonded to a Transition Metal.; 7.4.2. Formation of the Group--IIA--and --Inner Transition--Metal Bond; 7.4.2.1. in Metallic Systems; 7.4.2.2. in Coordination Compounds Containing a Group--IIA -- Transition-- and Inner--Transition--Metal Bond; 7.5. The Formation of the Group IA or IIA--Group 0 Element Bond; 8. Formation of the Bond to the Group--IB (Cu, Ag, Au) or --IIB (Zn, Cd, Hg) Elements; 8.1. Introduction; 8.2. Formation of the Group--IB or --IIB--Group--IB or --IIB Metal Bonds; 8.2.1. in Gold Cluster Compounds Containing the Au 3 , Au 4 , Au 5 , Au 6 , Au 7 , Au 8 , Au 9 , Au 11 , Au 13 and Au 55 Cores; 8.2.1.1. by Reduction of Au(I) Complexes; 8.2.1.2. from Reactions of Evaporated Au with Au(I) Complexes; 8.2.1.3. from the Conversion of Clusters; 8.2.2. in Other Metal--Metal Bonded Dimers and Clusters of Group--IB Elements; 8.2.2.1. Bare Metal Dimers and Clusters; 8.2.2.1.1. Metal--Vapor Cryochemistry 1 7 ; 8.2.2.1.2. Other Methods.; 8.2.2.2. Dimers and Clusters with Nonbridging Ligands; 8.2.2.2.1. Syntheses from Metal Vapors; 8.2.2.2.2. Other Methods.; 8.2.2.3. Dimers and Clusters with Bridging Ligands; 8.2.2.3.1. Compounds of Copper.; 8.2.2.3.2. Compounds of Silver.; 8.2.2.3.3. Compounds of Gold.; 8.2.3. In Univalent Compounds of Zinc and Cadmium; 8.2.3.1. Univalent Compounds of Zinc; 8.2. Formation of the Group--IB or --IIB--Group--IB or --IIB Metal Bonds; 8.2.3.2. Univalent Compounds of Cadmium; 8.2.4. in Mercury(I) Compounds from Mercury(II) Compounds; 8.2.4.1. Preparation of Simple Mercury(I) Compounds; 8.2.4.2. Complexes of Mercury(I); 8.2.4.2.1. Complexes of Mercury(I) with Oxygen--Donor Ligands.; 8.2.4.2.2. Complexes of Mercury(I) with Sulfur-- and Selenium--Donor Ligands.; 8.2.4.2.3. Complexes of Mercury(I) with Nitrogen--Donor Ligands.; 8.2.4.2.4. Complexes of Mercury(I) with Phosphorous--, Arsenic-- and Antimony--Donor Ligands.; 8.2.4.3. Preparation of Organomercury(I) Compounds; 8.2.5. Mercury Chain Compounds; 8.2.5.1. Mercury Chain Compounds in Liquid SO 2 ; 8.2.5.2. Mercury Chain Compounds in Molten AlCI 3 ; 8.3. Formation of the Group--IB (Cu, Ag, Au) or Group--IIB (Zn, Cd, Hg)-- Transition--Metal Bonds; 8.3.1. Introduction; 8.3.2. Group IB--Transition-- and Inner Transition--Metal Bonds; 8.3.2.1. by Coupling Carbonyl Anions with Complexes of the Group--IB Monohalides 1 ; 8.3.2.1.1. Formation of Bonds Between Transition Metals and Copper or Silver.; 8.3.2.1.2. Formation of Bonds Between Transition Metals and Gold.; 8.3.2.2. by Other Methods; 8.3.2.2.1. Reaction of Carbonyl Anions with Uncomplexed Derivatives of Group--IB Metals.; 8.3.2.2.2. Reaction of Carbonyl Hydrides with Complexes of Group--IB Metals.; 8.3.2.2.3. Reactions of Other Transition--Metal Complexes with Group--IB Compounds.; 8.3.2.2.4. Codeposition of Group--IB and Transition Metals To Give Bimetallic Clusters.; 8.3.2.2.5. Formation of Clusters Containing Group--IB and Transition Metals 1 ; 8.3.3. Synthesis of Group IIB--Transition-- and Inner--Transition--Metal Bonds; 8.3.3.1. by Reactions of Carbonyl Anions with Divalent Group--IIB Salts; 8.3.3.1.1. Derivatives of Zinc and Cadmium.; 8.3.3.1.2. Derivatives of Mercury.; 8.3.3.2. Reactions of Carbonyls and Substituted Carbonyls with Divalent Group--IIB Salts; 8.3.3.2.1. Derivatives of Zinc and Cadmium.; 8.3.3.2.2. Derivatives of Mercury.; 8.3.3.3. by Reactions of Other Transition--Metal Complexes with Group--IIB Derivatives; 8.3.3.4. by Insertion into a Metal--Metal Bond Insertion of a Group--IIB Element into Transition--Metal to Transition--Metal Bonds; 8.3.3.5. Other Synthetic Methods; 8.3.3.5.1. Reactions of Metals Not Involving Insertion or Exchange.; 8.3.3.5.2. Exchange.; 8.4. The Formation of the Group--IB or --IIB--Group 0 Element Bond; List of Abbreviations; Author Index; Compound Index; Subject Index

Product Details

  • publication date: 02/09/1991
  • ISBN13: 9780471186649
  • Format: Hardback
  • Number Of Pages: 576
  • ID: 9780471186649
  • weight: 1004
  • ISBN10: 0471186643

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