Ionic Processes in the Gas Phase: Advanced Study Institute on Chemistry of Ions in the Gas Phase : Papers (NATO Science Series C 118)
By: Almoster Ferreira (editor)Hardback
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The field of gas phase ion chemistry has undergone spectac- ular growth and development in the last decade. Ne\*! experimental techniques have developed and theoretical advancements in quantum chemistry and chemical dynamics have begun to provide quantitative information, deeper insights and important guideposts for experi- ments. The growing interaction between theoreticians and experi- mentalists is yielding scientific information of both basic and applied significance. The NATO Advanced Study Institute on Chemistry of Ions in the Gas Phase held at VimeirCl, Portugal, from 6 to 17 September 1982 took place four years after the 1978 Advanced Study Insti- tute on Kinetics of Ion-Molecule Reactions held at la Baule, France. New theoretical approaches and experimental techniques developed since then are included in this book. Fundamental aspects concerning the kinetics and dynamics of formation and decomposition of gaseous positive and negative ions, their structural charActerisation, energetics and thermochemistry are also discussed.
In addition, some recent innovative developments in the areas of photodissociation, multiphoton ionisation, photo- electron-photoion coincidence spectroscopy, selected ion flow tube technique, and other techniques will be fonnd. The success of the NATO Advanced Institute on Chemistry of Ions in the Gas Phase was mostly due to the high quality of the lectures, panel sessions, research review contributions and the ensuing important discussions which would informally continue after the scheduled sessions. All the participants were ulti- mately responsible for the attainment of the aims of the Institute.
Potential Energy Surfaces and Theory of Unimolecular Dissociation.- Scanning Methods for Double-Focussing Mass Spectrometers.- Charge Exchange Mass Spectrometry.- Isotope Exchange in Ion-Molecule Reactions.- Energetics and Dynamics of Ion-Molecule Reactions at Thermal Energies.- Recent Studies of Gas-Phase Reactions of Anions with Organic Molecules.- Gas-Phase Studies of the Influence of Solvation on Ion Reactivity.- Exothermic Bimolecular Ion Molecule Reactions with Negative Temperature Dependence.- Spectroscopic Structure and Radiationless Decay of Open-Shell Organic Cations.- Gas-Phase Ion Photodissociation.- Dissociation Dynamics of Energy Selected Ions Studied by one and Multiphoton Ionization.- Sift-Drift Studies of Anions.- Determinations of Gas-Phase Organic Ion Structures.- Carbon Skeletal Rearrangements Via Pyramidal Carbocations.- Low Rate Fragmentation Reactions of Gaseous Ions.- Applications of the Franck-Condon Factors to Polyatomic Molecules.- Ion Clusters: Summary of The Panel Discussion.- Ion Thermochemistry: Summary of the Panel Discussion.- Instrumentation: Summary of the Panel Discussion.
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- ID: 9789027716880
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