Isotope Effects in Gas-Phase Chemistry (ACS Symposium Series No. 502)
By: Jack A. Kaye (editor)Hardback
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Focuses on measurements and calculations of isotope effects in chemical reactions and photodissociation. Covers a variety of processes, ranging from the very simple (atom-diatom reactions) to the complex (multiligand coordination compounds) and includes both neutral and ionic species. Examines a variety of applications, including those to astrophysical, planetary, and atmospheric science. Both light- and heavy-atom isotope effects are covered.
Isotope Effects in Gas-Phase Chemical Reactions and Photodissociation Processes: Overview ; Variational Transition-State Theory with Multidimensional, Semiclassical, Ground-State Transmission Coefficients: Applications to Secondary Deuterium Kinetic Isotope Effects in Reactions Involving Methane and Chloromethane ; HN[2 and DN[2, Resonance Spectra: Scattering and Stabilization Calculations ; Isotope Effects in Addition Reactions of Importance in Combustion: Theoretical Studies of the Reactions CH+H[2 RTLT CH[3* RTLT CH[ + H ; Hydrogen Isotope Effects in Chemical Reactions and Photodissociations ; Isotope Effects at High Temperatures Studied by the Flash or Laser Photolysis-Shock Tube Technique ; Deuterium Substitution Used as a Tool for Investigating Mechanism of Gas-Phase Free-Radical Reactions ; Kinetic Isotope Effects in Gas-Phase Muonium Reactions ; Mass-Independent Isotopic Fractionations and their Applications ; Heavy Ozone Anomaly: Evidence for a Mysterious Mechanism ; Isotopic Study of the Mechanism of Ozone Formation ; Negative-Ion Formation by Rydberg Electron Transfer: Isotope-Dependent Rate Constants ; Isotope Effects in the Reactions of Atomic Ions with H[2, D[2 and HD ; Non-Mass-Dependent Isotope Effects in the Formation of O+: Evidence for a Symmetry Restriction ; Temperature, Kinetic Energy, and Rotational Temperature Effects in Four Reactions Involving Isotopes ; Isotope-Exchange Reactions Within Gas-Phase Protonated Cluster Ions ; Mechanisms for Isotopic Enrichment in Photochemical Reactions ; State-Selected Dissociation of trans-HONO(A~) and DONO(A~): Effect of Intramolecular Vibrational Dynamics on Fragmentation Rate, Stereochemistry, and Product Energy Distribution ; Isotope Dependence of the Methyl-Radical Rydberg 3 s Predissociation Dynamics ; Laser-Stimulated Selective Reactions and Synthesis of Isotopomers: New Strategies from Diatomic to Organometallic Molecules ; Multiphoton Ionization Dynamics Within (CH[3OH)[nO[2Cr(CO)[6 van der Waals Clusters: Isotope Effects in Intracluster Energy Transfer ; Deuterium Fractionation in Interstellar Space ; Deuterium in the Solar System ; Kinetic Isotope Effects and Their Use in Studying Atmospheric Trace Species: Case Study, CH[4 + OH ; Key Sulfur-Containing Compounds in the Atmosphere and Ocean: Determination by Gas Chromatography-Mass Spectrometry and Isotopically Labeled Internal Standards
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- ID: 9780841224711
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