Methods and Applications of Cycloaddition Reactions in Organic Syntheses

Methods and Applications of Cycloaddition Reactions in Organic Syntheses

By: Nagatoshi Nishiwaki (editor)Hardback

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Description

Although these reactions have been studied for a long time, cycloaddition chemistry makes frequent and considerable advances that requires chemists to keep constantly up-to-date with the practices and state-of-the-art. Bringing together the contributions from leading worldwide researchers, Methods and Applications of Cycloaddition Reactions in Organic Syntheses provides a valuable guidebook for synthetic organic chemists involved in chemical research, pharmaceuticals, and materials science to keep organic chemists updated and current in the practices of cycloadditions, a leading class of synthetic reaction.

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About Author

NAGATOSHI NISHIWAKI, PhD, is Professor of Chemistry at Kochi University of Technology, Japan. Dr. Nishiwaki has published over ninety scientific papers, twenty reviews and book chapters, and ten papers in chemical education. In addition, he has presented his research results at many scientific conferences.

Contents

PREFACE ix CONTRIBUTORS xi PART I [2+1] CYCLOADDITION 1 [2+1]-TYPE CYCLOPROPANATION REACTIONS 1 Akio Kamimura 2 N1 UNIT TRANSFER REACTION TO C--C DOUBLE BONDS 67 Satoshi Minakata, Youhei Takeda, and Kensuke Kiyokawa PART II [2+2] CYCLOADDITION 3 LEWIS BASE CATALYZED ASYMMETRIC FORMAL [2p2] CYCLOADDITIONS 89 Andrew D. Smith, James Douglas, Louis C. Morrill, and Edward Richmond PART III [2+2] AND [4+2]/[2+2] CYCLOADDITION 4 CATALYTIC [2p2] CYCLOADDITION OF SILYL ENOL ETHERS 115 Yosuke Yamaoka and Kiyosei Takasu PART IV [3+2] CYCLOADDITION 5 [3p2] CYCLOADDITION OF a,b-UNSATURATED METAL CARBENE COMPLEXES 135 Ryukichi Takagi and Manabu Abe 6 GEOMETRY-CONTROLLED CYCLOADDITION OF C-ALKOXYCARBONYL NITRONES: SYNTHETIC STUDIES ON NONPROTEINOGENIC AMINO ACIDS 151 Osamu Tamura 7 RECENT ADVANCES IN CATALYTIC ASYMMETRIC 1,3-DIPOLAR CYCLOADDITIONS OF AZOMETHINE IMINES, NITRILE OXIDES, DIAZOALKANES, AND CARBONYL YLIDES 175 Hiroyuki Suga and Kennosuke Itoh 8 CONDENSATION OF PRIMARY NITRO COMPOUNDS TO ISOXAZOLE DERIVATIVES: STOICHIOMETRIC TO CATALYTIC 205 Francesco De Sarlo and Fabrizio Machetti 9 CARBAMOYLNITRILE OXIDE AND INVERSE ELECTRON-DEMAND 1,3-DIPOLAR CYCLOADDITION 223 Nagatoshi Nishiwaki and Haruyasu Asahara PART V [3+2], [3+3], AND [4+2] CYCLOADDITION 10 CYCLOADDITION REACTIONS OF SMALL RINGS 241 Steven D. R. Christie and Hayley T. A. Watson PART VI [3+2] AND [5+1] CYCLOADDITION 11 DEVELOPMENT OF NEW METHODS FOR THE CONSTRUCTION OF HETEROCYCLES BASED ON CYCLOADDITION REACTION OF 1,3-DIPOLES 263 Yutaka Ukaji and Takahiro Soeta PART VII [3+3] CYCLOADDITION 12 A FORMAL [3p3] CYCLOADDITION APPROACH TO NATURAL PRODUCT SYNTHESIS 283 Jun Deng, Xiao-Na Wang, and Richard P. Hsung PART VIII [4+2] CYCLOADDITION 13 [4p2] CYCLOADDITION CHEMISTRY OF SUBSTITUTED FURANS 355 Scott Bur and Albert Padwa 14 SYNTHESIS OF SUBSTITUTED OLIGOACENES VIA DIELS ALDER REACTIONS AND SUBSTITUENT EFFECTS ON MOLECULAR STRUCTURE, PACKING ARRANGEMENT, AND SOLID-STATE OPTICAL PROPERTIES 407 Chitoshi Kitamura 15 CYCLOREVERSION APPROACH FOR PREPARATION OF LARGE p-CONJUGATED COMPOUNDS 429 Hidemitsu Uno PART IX [4+2]/[3+2] CYCLOADDITION 16 TANDEM [4p2]/[3p2] CYCLOADDITIONS 471 Ramil Y. Baiazitov and Scott E. Denmark PART X [5+1] CYCLOADDITION 17 TRANSITION METAL-CATALYZED OR -MEDIATED [5p1] CYCLOADDITIONS 551 Xu-Fei Fu and Zhi-Xiang Yu PART XI [4+3] CYCLOADDITION 18 [4p3] CYCLOADDITIONS OF ENOLSILANE DERIVATIVES 565 Sarah Y. Y. Lam and Pauline Chiu 19 APPLICATION OF THE [4p3] CYCLOADDITION REACTION TO THE SYNTHESIS OF NATURAL PRODUCTS 599 Darin E. Jones and Michael Harmata PART XII [5+2] CYCLOADDITION 20 RECENT DEVELOPMENTS IN THE [5p2] CYCLOADDITION 631 Herve Clavier and Helene Pellissier INDEX 655

Product Details

  • publication date: 25/03/2014
  • ISBN13: 9781118299883
  • Format: Hardback
  • Number Of Pages: 672
  • ID: 9781118299883
  • weight: 1726
  • ISBN10: 1118299884

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