Organosilicon Compounds: Theory and Experiment (Synthesis)

Organosilicon Compounds: Theory and Experiment (Synthesis)

By: Vladimir Ya Lee (editor)Paperback

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Description

Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon-silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds' structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry.

About Author

Dr. Lee has more than 30 years in experimental organometallic chemistry, specializing in the field of Main Group elements chemistry, primarily the heavier Group 14 elements (Si, Ge, Sn, Pb). In addition to his background and career as a synthetic organometallic chemist, he has extensive experience of the scientific writing and publishing processes as the author and co-author of more than 100 peer-reviewed research papers, published predominantly in high-ranking international journals (JACS, Angew. Chem., Organometallics, Inorg. Chem., etc.). He has also written scientific books contributions and co-authored six book chapters and one monograph, the latest of which are the following: (a) V. Ya. Lee and A. Sekiguchi. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds, Wiley, Chichester, 2010 [monograph]; (b) V. Ya. Lee and A. Sekiguchi. Multiply Bonded Compounds of the Heavy Group 14 Elements. In Comprehensive Inorganic Chemistry II (Eds. J. Reedijk and K. Poeppelmeier), Elsevier, Oxford, 2013, Vol. 1 (Vol. Ed.: T Chivers), Chapter 1.11.

Contents

I. Theory Chapter I.1 Nonclassical Organosilicon Compounds II. Experiment II.1. Synthesis II.1.1. Organosilicon Compounds of Tetracoordinate Silicon Chapter II.1.1.1. Transition Metal Complexes of Silicon (excluding silylene complexes) Chapter II.1.1.2. Silicon Cages and Clusters Chapter II.1.1.3. Chiral Organosilicon Compounds II.1.2. Organosilicon Compounds of Low-Coordinate Silicon Chapter II.1.2.1. Silicon-Centered Cations Chapter II.1.2.2. Silicon-Centered Radicals Chapter II.1.2.3. Silicon-Centered Anions Chapter II.1.2.4. Silylenes and Their Transition Metal Complexes Chapter II.1.2.5. Multiple Bonds to Silicon Chapter II.1.2.6. Silaaromatics and Related Compounds II.1.3. Organosilicon Compounds of Hypercoordinate Silicon Chapter II.1.3.1. Penta - and Hexacoordinated Silicon (IV) Compounds II.2. Physico-Chemical Studies Chapter II.2.1. X-Ray Crystallography of Organosilicon Compounds Chapter II.2.2. 29Si NMR Spectroscopy Chapter II.2.3. Thermochemistry of Organosilicon Compounds Chapter II.2.4. Photoelectron Spectroscopy of Organosilicon Compounds III. Applications Chapter III.1. Hydrosilylation of the Carbon-Carbon Multiple Bonds Chapter III.2. Polysilanes Chapter III.3. Siloxanes and Silicones Chapter III.4. Silicon-Based Dendrimers and Irregular Hyperbranched Polymers

Product Details

  • ISBN13: 9780128019818
  • Format: Paperback
  • Number Of Pages: 756
  • ID: 9780128019818
  • weight: 1520
  • ISBN10: 0128019816

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